- DCAO stands for Departamento de Ciencias de la Atmósfera y los Océanos (Spanish: Department of Atmospheric and Oceanic Sciences; Argentina)
- DCAO stands for Debt Collection Assistance Officer (US DoD TRICARE)
- DCAO stands for Defence Counsel Association of Ottawa (Canada)
- DCAO stands for Deputy Chief Administrative Officer (various locations)
- DCAO stands for Digital Commerce Advancement Organization (financial technologies)
DCAO